|Title of the idea:||Intramolecular hydroxylation of Allylic N-Oxides|
|Author of the idea:||Ramesha|
|Email of the firstname.lastname@example.org|
|Key words for search:||Dihydroxylation, Osmium tetroxide, N-Oxide, Hydrogen peroxide|
|Explain briefly the idea||
Sharpless dihydroxylation is normally done with N-Oxide and OsO4 in water. This can be extended to intramolecular dihydroxylation as represented. Sharpless epoxidation withallylic hydroperoxides is already known. But allylic N-oxide to dihydroxylation is not reported so far.
|Why do you think this idea will work?||Dihydroxylation of allylic or non allylic olefins of tert amines.|
|Do you have any experimental proof?||No|
|Literature reference||V. Van Rheenen, D. Y. Cha, W. M. Hartler, OSCV 6, 1988, P342|
|Where it is useful?||Academic|
|Do you plan to work on this idea in near future?||Yes|
|Interested in collaboration?||Yes|
|Nature of idea:||Theoretical/experimental|
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